1,236 research outputs found
Neutron scattering study of a quasi-2D spin-1/2 dimer system Piperazinium Hexachlorodicuprate under hydrostatic pressure
We report inelastic neutron scattering study of a quasi-two-dimensional S=1/2
dimer system Piperazinium Hexachlorodicuprate under hydrostatic pressure. The
spin gap {\Delta} becomes softened with the increase of the hydrostatic
pressure up to P= 9.0 kbar. The observed threefold degenerate triplet
excitation at P= 6.0 kbar is consistent with the theoretical prediction and the
bandwidth of the dispersion relation is unaffected within the experimental
uncertainty. At P= 9.0 kbar the spin gap is reduced to 0.55 meV from 1.0 meV at
ambient pressure.Comment: 4 pages, 5 figure
High Resolution Study of Spin Excitations in the Shastry-Sutherland Singlet Ground State of SrCu2(BO3)2
High resolution, inelastic neutron scattering measurements on SrCu2(BO3)2
reveal the dispersion of the three single triplet excitations continuously
across the (H,0) direction within its tetragonal basal plane. These
measurements also show distinct Q dependencies for the single and multiple
triplet excitations, and that these excitations are largely dispersionless
perpendicular to this plane. The temperature dependence of the intensities of
these excitations is well described as the complement of the dc-susceptibility
of SrCu2(BO3)2.Comment: 4 pages, 4 figures. Submitted to PR
Rotational Dynamics of Organic Cations in CH3NH3PbI3 Perovskite
Methylammonium lead iodide (CH3NH3PbI3) based solar cells have shown
impressive power conversion efficiencies of above 20%. However, the microscopic
mechanism of the high photovoltaic performance is yet to be fully understood.
Particularly, the dynamics of CH3NH3+ cations and their impact on relevant
processes such as charge recombination and exciton dissociation are still
poorly understood. Here, using elastic and quasi-elastic neutron scattering
techniques and group theoretical analysis, we studied rotational modes of the
CH3NH3+ cation in CH3NH3PbI3. Our results show that, in the cubic (T > 327K)
and tetragonal (165K < T < 327K) phases, the CH3NH3+ ions exhibit four-fold
rotational symmetry of the C-N axis (C4) along with three-fold rotation around
the C-N axis (C3), while in orthorhombic phase (T < 165K) only C3 rotation is
present. Around room temperature, the characteristic relaxation times for the
C4 rotation is found to be ps while for the C3 rotation ps. The -dependent
rotational relaxation times were fitted with Arrhenius equations to obtain
activation energies. Our data show a close correlation between the C4
rotational mode and the temperature dependent dielectric permittivity. Our
findings on the rotational dynamics of CH3NH3+ and the associated dipole have
important implications on understanding the low exciton binding energy and slow
charge recombination rate in CH3NH3PbI3 which are directly relevant for the
high solar cell performance
A Neutron Elastic Diffuse Scattering Study of PMN
We have performed elastic diffuse neutron scattering studies on the relaxor
Pb(MgNb)O (PMN). The measured intensity distribution near a
(100) Bragg peak in the (hk0) scattering plane assumes the shape of a butterfly
with extended intensity in the (110) and (10) directions. The
temperature dependence of the diffuse scattering shows that both the size of
the polar nanoregions (PNR) and the integrated diffuse intensity increase with
cooling even for temperatures below the Curie temperature K.Comment: Submitted to PR
Revisiting Static and Dynamic Spin Ice Correlations in Ho2Ti2O7
Elastic and inelastic neutron scattering studies have been carried out on the
pyrochlore magnet Ho2Ti2O7. Measurements in zero applied magnetic field show
that the disordered spin ice ground state of Ho2Ti2O7 is characterized by a
pattern of rectangular diffuse elastic scattering within the [HHL] plane of
reciprocal space, which closely resembles the zone boundary scattering seen in
its sister compound Dy2Ti2O7. Well-defined peaks in the zone boundary
scattering develop only within the spin ice ground state below ~ 2 K. In
contrast, the overall diffuse scattering pattern evolves on a much higher
temperature scale of ~ 17 K. The diffuse scattering at small wavevectors below
[001] is found to vanish on going to Q=0, an explicit signature of expectations
for dipolar spin ice. Very high energy-resolution inelastic measurements reveal
that the spin ice ground state below ~ 2 K is also characterized by a
transition from dynamic to static spin correlations on the time scale of
10^{-9} seconds. Measurements in a magnetic field applied along the
[10] direction in zero-field cooled conditions show that the system
can be broken up into orthogonal sets of polarized alpha chains along
[10] and quasi-one-dimensional beta chains along [110]. Three
dimensional correlations between beta chains are shown to be very sensitive to
the precise alignment of the [10] externally applied magnetic field.Comment: 11 pages, 10 figures. Submitted for publicatio
Nano-magnetic droplets and implications to orbital ordering in La1-xSrxCoO3
Inelastic cold neutron scattering on LaCoO3 provided evidence for a distinct
low energy excitation at 0.6 meV coincident with the thermally induced magnetic
transition. Coexisting strong ferromagnetic (FM) and weaker antiferromagnetic
(AFM) correlations that are dynamic follow the activation to the excited state,
identified as the intermediate S=1 spin triplet. This is indicative of
dynamical orbital ordering favoring the observed magnetic interactions. With
hole doping as in La1-xSrxCoO3, the FM correlations between Co spins become
static and isotropically distributed due to the formation of FM droplets. The
correlation length and condensation temperature of these droplets increase
rapidly with metallicity due to the double exchange mechanism.Comment: To appear in Phys. Rev. Let
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